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Ammonium Bifluoride CAS 1341-49-7

Molecular formula: F2H5N
Molecular weight: 57.04
Melting Point: 125 °C(lit.)
Boiling point: 230 °C
Flashing point: 238°C
Density: 1,5 g/cm3
Soluble: 630 g/L (20 ºC)
Sensibility: Hygroscopic
  • 1341-49-7

  • MOSINTER

  • 1341-49-7

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Supply Capacity

Payment Terms:

T/T, WU

Production Capacity:

5000T/year

Min. Order:

25KG

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Ocean, Air, Land

Delivery Date:

7 days

 

Ammonium Bifluoride

CAS: 1341-49-7

Item

Index

Appearance

White Orthorhombic Crystal

NH4HF2, %≥

98.0

loss on drying, %≤

1.0

Content of residue on ignition, %≤

0.2

Sulfate(base on SO4) content, %≤

0.1

Content of ammonium fluosilicate [(NH4)SiF6]   , %≤

2.0


Ammonium hydrogen fluoride is the inorganic compound with the formula NH4HF2 or NH4F·HF. It is produced from ammonia and hydrogen fluoride. This colourless salt is a glass-etchant and an intermediate in a once-contemplated route to hydrofluoric acid.

Structure

Ammonium bifluoride, as its name indicates, contains a bifluoride, or hydrogen(difluoride) anion: HF2−. This centrosymmetric triatomic anion features the strongest known hydrogen bond, with a F−H length of 114 pm.  and a bond energy greater than 155 kJ mol−1.

In solid [NH4][HF2], each ammonium cation is surrounded by four fluoride centers in a tetrahedron, with hydrogen-fluorine hydrogen bonds present between the hydrogen atoms of the ammonium ion and the fluorine atoms. Solutions contain tetrahedral [NH4]+ cations and linear [HF2]− anions.

 


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